| 摘要: |
| 以2,6-二甲基吡啶和2,6-二溴吡啶为原料,经锂试剂分别与光学活性的樟脑、薄荷酮和3-甲酰基蒎烷反应合成了4个新的手性吡啶类化合物。测定了它们在苯甲醛和二乙基锌加成反应中的不对称诱导性能。 |
| 关键词: 吡啶衍生物 烷基化反应 不对称合成 |
| DOI： |
| 投稿时间：1994-06-08 |
| 基金项目: |
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| Studies on Synthesis of New Chiral Ligands Containing Pyridine and Their Properties in Asymmeiric Induction |
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| Abstract: |
| Several chiral ligands containing pyridine were prepared from 2,6-dimethyl pyridine or 2,6- dibromopyridine via their lithium reagents.Their asymmetric induction was observed in the reaction of benzaldehyde and diethyl zinc. |
| Key words: pyridine derivatives alkylating reaction asymmetric synthesis |
